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Behaviour of Terpene Peroxides from Abietic Acid in the Presence of Heme and Non-Heme Iron(II)

✍ Scribed by Ursula Muellner; Antje Huefner; Ernst Haslinger

Publisher: Elsevier Science
Year: 2000
Tongue: French
Weight: 148 KB
Volume: 56
Category: Article
ISSN: 0040-4020
DOI: 10.1016/s0040-4020(00)00312-4

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✦ Synopsis

AbstractÐIn aqueous acetonitrile with FeCl 2 or hemin/l-cysteine, a peroxide (4) obtained from abietic acid by photosensitized air oxidation undergoes rearrangement to give a diepoxide and two spiro compounds as major products.

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