The Reductive Conversion of Some Cyclic
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Vladimir AndrejeviΔ; Mira BjelakoviΔ; Milan M. MihailoviΔ; Mihailo Lj. Mihailovi
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Article
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1985
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John Wiley and Sons
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German
β 172 KB
Unsubstituted medium-ring 1,2-epoxycycloalkanes and certain vie-epoxyalkanes are reduced to the corresponding alcohols very slowly when LiAIH, alone is used as reducing agent. However, the combination of LiA1H4 and AICI,, in a 2:l molar ratio (with respect to 1 mol-equiv. of epoxide) used in refluxi