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Base-induced Rearrangements. Action of Iodide Ion on Certain 1,3-Dihalides

โœ Scribed by Schubert, W. M.; Leahy, Sidney M.


Book ID
121488898
Publisher
American Chemical Society
Year
1957
Tongue
English
Weight
719 KB
Volume
79
Category
Article
ISSN
0002-7863

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The base-induced rearrangement of endo-7
โœ I. Watt ๐Ÿ“‚ Article ๐Ÿ“… 1978 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 207 KB

We have recently described' rapid reversible 3,7-hydride transfer in the alkoxide of exo-bicyclo[3.3.11 nonan-7-ol-3-one (1). We now report the base-induced rearrangement of the title compound (3) to anti-7,7-dimethylbicycl0[3.3.l]nonan-9-ol-3-one (4) , a process involving 3,9-hydride transfer withi