The base-induced rearrangement of endo-7
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I. Watt
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Article
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1978
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Elsevier Science
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French
โ 207 KB
We have recently described' rapid reversible 3,7-hydride transfer in the alkoxide of exo-bicyclo[3.3.11 nonan-7-ol-3-one (1). We now report the base-induced rearrangement of the title compound (3) to anti-7,7-dimethylbicycl0[3.3.l]nonan-9-ol-3-one (4) , a process involving 3,9-hydride transfer withi