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Base-induced rearrangement of oxiranylsilacyclobutane into silacyclopentane. Application to stereoselective synthesis of 4-alken-1-ol and 1,4,5-triol

โœ Scribed by Kozo Matsumoto; Yoshihiro Takeyama; Koichiro Oshima; Kiitiro Utimoto


Publisher
Elsevier Science
Year
1991
Tongue
French
Weight
158 KB
Volume
32
Category
Article
ISSN
0040-4039

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ChemInform Abstract: Base-Induced Rearra
โœ R. P. L. BELL; A. SOBOLEV; J. B. P. A. WIJNBERG; A. GROOT ๐Ÿ“‚ Article ๐Ÿ“… 2010 ๐Ÿ› John Wiley and Sons โš– 42 KB

## Base-Induced Rearrangement of Perhydronaphthalene-1,4-diol Monosulfonate Esters to 11-Oxatricyclo[5.3.1.0 2,6 ]undecanes. Total Synthesis of Furanether B. -In the presence of LiAlH(O-tBu) 3 the mesylate (I) is found to undergo selective rearrangement to the tricyclic derivative (II). This rear