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Base-induced reactions of α,β-dihydroxysilanes: stereochemistry and mechanisms

✍ Scribed by Paul F. Hudrlik; G. Nagendrappa; Ashok K. Kulkarni; Anne M. Hudrlik

Book ID
104244769
Publisher
Elsevier Science
Year
1979
Tongue
French
Weight
315 KB
Volume
20
Category
Article
ISSN
0040-4039

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✦ Synopsis

Cyclic d,fi-dihydroxysilanes undergo base-induced elimination reactions if the silicon and the @-OH can be anti; otherwise protiodesilylation predominates.

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## Abstract The mechanisms for elimination of H~2~O from acenaphthenol and of AcOH from acetoxyacenaphthene under low energy conditions have been determined, using regiospecific and stereospecific deuterium labeling probes, and by measurement of ionization and appearance potentials for alternative