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Stereochemistry and mechanism of electron impact induced elimination reactions in acenaphthenol and acetoxyacenaphthene

✍ Scribed by Daryl D. Manhart; Peter Brown; Duncan H. Hunter

Publisher
John Wiley and Sons
Year
1977
Tongue
English
Weight
659 KB
Volume
12
Category
Article
ISSN
1076-5174

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✦ Synopsis

Abstract

The mechanisms for elimination of H~2~O from acenaphthenol and of AcOH from acetoxyacenaphthene under low energy conditions have been determined, using regiospecific and stereospecific deuterium labeling probes, and by measurement of ionization and appearance potentials for alternative pathways. Both concerted and stepwise processes must be invoked in order to explain the experimental data. Proximity effects appear to be the most important factors in determining mechanistic type.

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