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Base hydrolysis of pentaammine complexes of cobalt(III): structure, reactivity, and lifetime of the intermediates

✍ Scribed by Rotzinger, Francois P.

Book ID
127336210
Publisher
American Chemical Society
Year
1988
Tongue
English
Weight
653 KB
Volume
27
Category
Article
ISSN
0020-1669

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πŸ“œ SIMILAR VOLUMES

Base Hydrolysis of (Acidato)(Pentaamine)
Base Hydrolysis of (Acidato)(Pentaamine) Complexes with Inert Metal Centers: Electronic Structure of the Intermediates, Requirements for Their Formation, and the Unique Reactivity of the Complexes of Cobalt(III)
✍ FranΓ§ois P. Rotzinger; Jacques Weber; Claude Daul πŸ“‚ Article πŸ“… 1991 πŸ› John Wiley and Sons 🌐 German βš– 933 KB

## Abstract Molecular‐orbital calculations have been performed for the conjugate base __cis__‐[Co(NH~3~)~4~(NH~2~)Cl]^+^ and __trans__‐[M(NH~3~)~4~(NH~2~)Cl]^+^ (M = Cr^III^, Co^III^, and Rh^III^), the hexacoordinated intermediates __cis‐__ and __trans__‐[Co(NH~3~)~4~(NH~2~)…Cl]^+^, the square‐pyra