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Base-catalyzed nitrito to nitro linkage isomerization of cobalt(III), rhodium(III), and iridium(III) pentaammine complexes

✍ Scribed by Jackson, W. Gregory; Lawrance, Geoffrey A.; Lay, Peter A.; Sargeson, Alan M.


Book ID
119963286
Publisher
American Chemical Society
Year
1980
Tongue
English
Weight
1013 KB
Volume
19
Category
Article
ISSN
0020-1669

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The nitrito to nitro spontaneous isomerization reaction of the complexes [Co(MeNH 2 ) 5 (ONO)] 2 + , cis-[Co(MeNH 2 )- trans-[CoL 14 (ONO)] 2 + and cis-[CoL 14 (ONO)] 2 + has been studied as a function of temperature and pressure. The corresponding base-catalyzed reactions of the systems with monod