✦ LIBER ✦

Base hydrolysis and mercury(II)-catalysed aquation of the chloropentamine cis-[Co(en)2(β-alaOH)Cl]2+ and the reactions of cis-[Co(en)2(β-alaOMe)Cl]2+ in basic solution

✍ Scribed by Robert W. Hay; Ross Bennett; Arup K. Basak

Publisher: Elsevier Science
Year: 1996
Tongue: English
Weight: 494 KB
Volume: 15
Category: Article
ISSN: 0277-5387
DOI: 10.1016/0277-5387(95)00334-2

No coin nor oath required. For personal study only.

📜 SIMILAR VOLUMES

Ligand displacement reactions from the c

Ligand displacement reactions from the coordination sphere of cobalt complexes. Part II: The displacement of ligands of [cis-Co(en)2Cl2]Cl by potassium squarate. The crystal and molecular structure of a compound with idealized formula of [cis-Co(en)2(H2O)Br]2[trans-(C2O42−(C2O4H−)Co-trans-(H2O)2(OH)2]Br2(I)

✍ Jiwen Cai; Ivan Bernal; Frank Fronczek; Steven F. Watkins 📂 Article 📅 1996 🏛 Springer 🌐 English ⚖ 539 KB

On the mechanism of the Hg2+ and base in

On the mechanism of the Hg2+ and base induced hydrolysis reactions of the β2-(RR, SS)-Co (trien) (glyOR)Cl2+ions (R = H, C2H5), evidence for the site of deprotonation in the reactive conjugate base

✍ David A. Buckingham; Werner Marty; Alan M. Sargeson 📂 Article 📅 1978 🏛 John Wiley and Sons 🌐 German ⚖ 894 KB

## Acid hydrolysis of the ester function in A-( -)589-fi2-(RR)-[Co (trien) (glyOEt)C1I2+ (( -)-1) produces optically pure A-( -)589$2-(RR)-[CO (trien) (glyOH)C1I2+ (( -)-4). Hg2+ induced removal of chloride in (-)-4 follows the rate law kobs=kHg [Hg2+] with kHg=(1.36+0.03)x 1 0 -2 ~-l s -' , 25",

The phenomenon of conglomerate crystalli

The phenomenon of conglomerate crystallization: XXXVII: The crystallization behavior of the Cr(III) and Co(III) amine carbonates [Cr(en)2CO3]I (I) and NH4{[cis-β-Co(trien)Co3]2}(PF6)3(II)

✍ Ivan Bernai; Jiwen Cai; James Cetrullo; Salah S. Massoud 📂 Article 📅 1994 🏛 Springer 🌐 English ⚖ 690 KB