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Base-Catalyzed Reactions in NH 3 -Enriched Near-Critical Water

✍ Scribed by Lu, Xiuyang; Li, Zhun; Gao, Fei


Book ID
126061994
Publisher
American Chemical Society
Year
2006
Tongue
English
Weight
159 KB
Volume
45
Category
Article
ISSN
0888-5885

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## Abstract The base‐catalyzed linkage isomerization of [Co(NH~3~)~5~‐ONO]^2+^ to the nitro [(NH~3~)~5~Co‐NO~2~]^2+^ form is studied in various isodielectric water–cosolvent mixtures (methanol, ethanol, __tert__‐butyl alcohol, and 2‐propanol) at 298 K. In all cases, except for methanol–water mixtur