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Base-catalyzed epimerization of the butenolide in annonaceous acetogenins

✍ Scribed by Qian Yu; Yikang Wu; Yu-Lin Wu; Li-Jun Xia; Min-Hua Tang


Publisher
John Wiley and Sons
Year
2000
Tongue
English
Weight
89 KB
Volume
12
Category
Article
ISSN
0899-0042

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✦ Synopsis


The elusive epimerization process in the chiral butenolide moiety of Annonaceous acetogenins was examined under several sets of conditions commonly used for elimination leading to the ␣,␀-unsaturated lactone and the results provide practical guidance in choosing elimination conditions.


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Using countercurrent chromatography to a
✍ D. Craig Hopp; Walter D. Conway; Jerry L. McLaughlin πŸ“‚ Article πŸ“… 1999 πŸ› John Wiley and Sons 🌐 English βš– 114 KB πŸ‘ 1 views

Three new Annonaceous acetogenins, (2,4-cis and trans)-9-hydroxy asimicinone (1), (2,4-cis and trans)squamoxinone B (2) and (2,4-cis and trans) squamoxinone C (3), were isolated from the bark of Annona squamosa with the help of countercurrent chromatography. Additionally found was isoannoreticuin (4