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Barrier to internal rotation in amides. IV. N,N-Dimethylamides. Substituent and solvent effects

✍ Scribed by Drakenberg, Torbjorn; Dahlqvist, Kjell Ivar; Forsen, Sture

Book ID
121430306
Publisher
American Chemical Society
Year
1972
Tongue
English
Weight
706 KB
Volume
76
Category
Article
ISSN
0022-3654

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✍ K. Spaargaren; P. K. Korver; P. J. Der Van Haak; Th. J. de Boer πŸ“‚ Article πŸ“… 1971 πŸ› John Wiley and Sons 🌐 English βš– 472 KB πŸ‘ 1 views

Amide-rotational barriers obtained with a total line shape analysis of a series of parasubstituted N,N-dimethylbenzamides and -cinnamamides are correlated with the result of an H.M.O. ## (a ~~1 . 4 ) calculation. There is no difference in the activation parameters at a concentration of 0.25 M and