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Solvent dependence of the barrier to the Ph-N internal rotation in N-methylaniline

✍ Scribed by Frank A.L. Anet; Xiao-hui Ji


Publisher
Elsevier Science
Year
1984
Tongue
French
Weight
104 KB
Volume
25
Category
Article
ISSN
0040-4039

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## Abstract The barriers to rotation about the C(O)ο£ΏN bond for 13 α‐alkyl‐ and α‐halo‐substituted __N__‐theyl‐__N__‐methylamides were determined by ^1^H NMR spectroscopy at coalescence temperature. Plots of Gibbs free energy (Ξ”__G__Β°) and Gibbs energy of activation (Ξ”__G__‑) values against Charton'