Reaction of zinc 5,15-bis(3,5-di-tert-butylphenyl)porphyrin and 10,20-di-CF 3 -porphyrins as the minor products. The direct trifluoromethylation is effective for preparation of with S-(trifluoromethyl)-3,7-dinitrobenzothiophene trifluoromethanesulfonate in tetrahydrofuran gave the 10-tri-longer-wave
โฆ LIBER โฆ
Barbituric acid functionalized porphyrins and chlorins.
โ Scribed by Byron C. Robinson; Alan R. Morgan
- Book ID
- 108380412
- Publisher
- Elsevier Science
- Year
- 1993
- Tongue
- French
- Weight
- 250 KB
- Volume
- 34
- Category
- Article
- ISSN
- 0040-4039
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Reactions of vinylchlorins and vinylporphyrins with N,N-dimethylmethyleneammonium iodide ("Eschenmoser's Reagent") gives Man&h adducts in which substitution (with CH2NMe2) has taken place on the terminal carbon of the vinyl group to yield a trans-3-(N,Ndimethylaminomethyl)prop-1 -enyl derivative. Un