Enantioselective reduction of 2-allyl-2-carboethoxy-cyclopentanone (2) was accomplished in high enantiomeric excess (> 99%), using baker's yeast in the presence of CuO, to obtain the (+)-2-allyl-2carboethoxycyclopentanol derivative (6). This methodology also provides an entry to corresponding p-keto
✦ LIBER ✦
Baker′s Yeast-Mediated Regioselective Reduction of 2,4-Dinitroacylanilines: Synthesis of 2-Substituted 6-Nitrobenzimidazoles.
✍ Scribed by Luis F. Olguin; Manuel Jimenez-Estrada; Eduardo Barzana; Arturo Navarro-Ocana
- Publisher
- John Wiley and Sons
- Year
- 2005
- Weight
- 18 KB
- Volume
- 36
- Category
- Article
- ISSN
- 0931-7597
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