Baeyer-Villiger Oxidation of Ketones Using Molecular Oxygen and Benzaldehyde in the Absence of Metal Catalysts
✍ Scribed by Kaneda, Kiyotomi; Ueno, Shinji; Imanaka, Toshinobu; Shimotsuma, Emi; Nishiyama, Yutaka; Ishii, Yasutaka
- Book ID
- 120021218
- Publisher
- American Chemical Society
- Year
- 1994
- Tongue
- English
- Weight
- 275 KB
- Volume
- 59
- Category
- Article
- ISSN
- 0022-3263
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📜 SIMILAR VOLUMES
Metal (Me: Fe, Co, Ni or Cu) containing Mg-Al hydrotalcite-type anionic clay catalysts have been prepared by adopting the "memory effect" of hydrotalcite and tested for Baeyer-Villiger oxidation of ketones. Mg-Al hydrotalcite was calcined to the mixed oxide and dipped in an aqueous solution of metal
Multi-metallic hydrotalcites consisting of magnesium, aluminum, and iron, or copper elements were prepared, which catalyzed the Baeyer-Villiger oxidation using a combination system of molecular oxygen and benzaldehyde. In particular, the Mg-Al\(\mathrm{Fe}-\mathrm{CO}_{3}\) hydrotalcite efficiently