Baeyer–Villiger oxidation of ketones in ionic liquids using molecular oxygen in the presence of benzaldehyde
✍ Scribed by Anna Chrobok
- Book ID
- 108283252
- Publisher
- Elsevier Science
- Year
- 2010
- Tongue
- French
- Weight
- 729 KB
- Volume
- 66
- Category
- Article
- ISSN
- 0040-4020
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📜 SIMILAR VOLUMES
Multi-metallic hydrotalcites consisting of magnesium, aluminum, and iron, or copper elements were prepared, which catalyzed the Baeyer-Villiger oxidation using a combination system of molecular oxygen and benzaldehyde. In particular, the Mg-Al\(\mathrm{Fe}-\mathrm{CO}_{3}\) hydrotalcite efficiently
## Abstract The reaction is applied to a variety of cyclic and linear ketones and is carried out in [bmim]BF~4~.
Metal (Me: Fe, Co, Ni or Cu) containing Mg-Al hydrotalcite-type anionic clay catalysts have been prepared by adopting the "memory effect" of hydrotalcite and tested for Baeyer-Villiger oxidation of ketones. Mg-Al hydrotalcite was calcined to the mixed oxide and dipped in an aqueous solution of metal