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Back Cover: Single-Particle and Ensemble Diffusivities—Test of Ergodicity (Angew. Chem. Int. Ed. 5/2012)

✍ Scribed by M. Sc. Florian Feil; Dr. Sergej Naumov; Prof. Dr. Jens Michaelis; Dr. Rustem Valiullin; Prof. Dr. Dirk Enke; Prof. Dr. Jörg Kärger; Prof. Dr. Christoph Bräuchle

Publisher
John Wiley and Sons
Year
2011
Tongue
English
Weight
961 KB
Volume
51
Category
Article
ISSN
0044-8249

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✦ Synopsis

Coincidence …

… between the mean-squared displacements determined for the same molecule over sequential time intervals and for all molecules over the same time interval follows as a consequence of the ergodic theorem. In their Communication on page 1152 ff., C. Bräuchle et al. confirm experimentally this fundamental principle of thermodynamics by diffusion studies using fluorescence microscopy and NMR spectroscopy with pulsed field gradients.

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