in ethanol 1) +AzH in CH 3 NO 2 2) AcONH 4 (a) (b) 4-Azulen-1-yl substituted 2,6-dimethyl-and 2,6-diphenyl-pyridines are obtained in good yields from the reaction of corresponding 4-azulen-1-yl-pyranylium salts and ammonium acetate in ethanol or starting from 4-chloro-2,6-diphenyl-pyranylium salts
Azulene-Substituted Pyridines and Pyridinium Salts. Synthesis and Structure. Part 1. Azulene-Substituted Pyridines.
โ Scribed by Alexandru C. Razus; Liviu Birzan; Claudia Pavel; Oana Lehadus; Andreea Corbu; Filip Chiraleu; Cristian Enache
- Publisher
- John Wiley and Sons
- Year
- 2007
- Weight
- 27 KB
- Volume
- 38
- Category
- Article
- ISSN
- 0931-7597
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ClO 4 -N + Me(Ph) R Az Me(Ph) R 1 ClO 4 -R 1 = Me, Bu, iPr, Bn, Ph, tBu 4-Azulen-1-yl substituted 2,6-dimethyl-and 2,6-diphenyl-pyridinium salts are obtained in yields between 50 % and 100 % in the reaction of corresponding 4-azulen-1-yl-pyranylim salts and various amines. The effects of amine stru