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Azophilic addition of alkyllithium reagents to fluorenimines. The synthesis of secondary amines

โœ Scribed by Dai, Wei; Srinivasan, Rajgopal; Katzenellenbogen, John A.


Book ID
120976714
Publisher
American Chemical Society
Year
1989
Tongue
English
Weight
656 KB
Volume
54
Category
Article
ISSN
0022-3263

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Grignard reagents add to ketonirrones in a nonpolar solvent to afford N,N-dialkylhydroxylamines in good yieids and with liiule compeling proton Paqfer. ## Deoxygenalion of the crude hydroxylatrSnes with carbon disulfide then compleres an eficient general synthetic route to hindered set-alkyl-lert-a