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Aziridine-Derived Iminophosphine Ligands in Palladium-Catalyzed Allylic Substitution.

✍ Scribed by Shadi Dalili; Aldo Caiazzo; Andrei K. Yudin

Publisher: John Wiley and Sons
Year: 2005
Weight: 16 KB
Volume: 36
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.200511049

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✦ Synopsis

Enantioselective syntheses O 0031

Aziridine-Derived Iminophosphine Ligands in Palladium-Catalyzed Allylic Substitution. -In the palladium-catalyzed allylic substitution reaction of acetate (II) with malonate (III), derivative (Ia) provides the best enantioselectivity in comparison to six other imines of type (I). -(DALILI, S.; CAIAZZO, A.

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