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Azido-Schmidt reaction for the formation of amides, imides and lactams from ketones in the presence of FeCl3

✍ Scribed by J.S. Yadav; B.V. Subba Reddy; U.V. Subba Reddy; K. Praneeth

Publisher: Elsevier Science
Year: 2008
Tongue: French
Weight: 197 KB
Volume: 49
Category: Article
ISSN: 0040-4039
DOI: 10.1016/j.tetlet.2008.05.113

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✦ Synopsis

Ketones undergo smooth rearrangement with TMSN 3 in the presence of FeCl 3 under extremely mild conditions to provide the corresponding amides, imides and lactams in good yields with high selectivity. This method is very useful for the preparation of a wide range of amides, imides and lactams from ketones. The use of FeCl 3 makes this method simple, convenient and cost-effective.

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