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A novel synthesis of cyclopropyl lactam and amide from cis-2-aryl-3-benzoyl-1,1-dicynocyclopropane with H2O2 in the presence of NaHCO3

✍ Scribed by Zhongjiao Ren; Jie Chen; Yeying Lu; Danyi Wu; Weiguo Cao


Publisher
Journal of Heterocyclic Chemistry
Year
2007
Tongue
English
Weight
289 KB
Volume
44
Category
Article
ISSN
0022-152X

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✦ Synopsis


Abstract

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The process for preparation of cyclopropyl lactam and amide from cis‐2‐aryl‐3‐benzoyl‐1,1‐dicynocyclopropane with H~2~O~2~ in the Presence of NaHCO~3~ is described. The highly stereoselective conversion of monocyano group to amide has been carried out in the present method.


πŸ“œ SIMILAR VOLUMES


Novel Procedure for Highly Stereoselecti
✍ Zhongjiao Ren; Weiguo Cao; Jie Chen; Yeying Lu πŸ“‚ Article πŸ“… 2007 πŸ› John Wiley and Sons βš– 18 KB πŸ‘ 2 views

## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract, please click on HTML or PDF.

A novel synthesis of 5-aryl-3-phenylpyra
✍ Zhongjiao Ren; Weiguo Cao; Jie Chen; Yu Wang; Weiyu Ding πŸ“‚ Article πŸ“… 2006 πŸ› Journal of Heterocyclic Chemistry 🌐 English βš– 427 KB πŸ‘ 1 views

A new process for synthesis of 5-aryl-3-phenylpyrazole is achieved. The regioselective ring-opening reaction of 2-aryl-3-benzoyl-1,1-cyclopropanedicarbonitrile with hydrazine plays a crucial role in the described process.