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Azaenolates of 2-Chloromethyl-4-methoxymethyl-5-phenyl-2-oxazoline − A Highly Diastereo- and Enantioselective Synthesis of Oxazolinyloxiranes

✍ Scribed by Vito Capriati; Saverio Florio; Renzo Luisi

Publisher: John Wiley and Sons
Year: 2001
Tongue: English
Weight: 306 KB
Volume: 2001
Category: Article
ISSN: 1434-193X
DOI: 10.1002/1099-0690(200106)2001:11<2035::aid-ejoc2035>3.0.co;2-r

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✦ Synopsis

The oxazoline-derived titanium azaenolate 6 couples highly stereoselectively with aldehydes affording highly optically pure oxazolinyloxiranes 7. The epoxide 7a has been deblocked to form the optically pure formyl oxirane 9. In con- [a

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