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Aza-Crown Tetrathiafulvalene Derivatives: Synthesis, X-ray Structure, and Metal Complexation Study

✍ Scribed by Franck Le Derf; Marc Sallé; Nicolas Mercier; Jan Becher; Pascal Richomme; Alain Gorgues; Jesus Orduna; Javier Garín

Publisher
John Wiley and Sons
Year
1998
Tongue
English
Weight
334 KB
Volume
1998
Category
Article
ISSN
1434-193X

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✦ Synopsis

The synthesis of new aza-macrocyclic tetrathiafulvalene electrochemical properties of these redox-active macrocyclic ligands are studied by cyclic voltammetry. Their complexing (TTF) derivatives is described, with a view to limiting the structural distortion of the redox-active TTF moiety and to ability towards silver ions is evaluated by FAB mass spectrometry. favour metal complexation. An X-ray diffraction determination of one of these crown systems is provided. The

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