✦ LIBER ✦

Synthesis and X-ray Structures of New Mononuclear and Dinuclear Diimine Complexes of Late Transition Metals

✍ Scribed by Timo V. Laine; Martti Klinga; Markku Leskelä

Publisher: John Wiley and Sons
Year: 1999
Tongue: English
Weight: 254 KB
Volume: 1999
Category: Article
ISSN: 1434-1948
DOI: 10.1002/(sici)1099-0682(199906)1999:6<959::aid-ejic959>3.0.co;2-z

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✦ Synopsis

Synthesis of new palladium(II) (1), nickel(II) (2a and 2b), and single-crystal X-ray diffraction. The Pd II compound exists in the monomeric form whereas the nickel complexes were cobalt(II) (3) complexes bearing the unsymmetrical, bidentate nitrogen ligand 2,6-bis(1-methylethyl)-N-(2-observed as centrosymmetric dimers with slightly distorted square-pyramidal coordination sphere around each nickel pyridinylmethylene)phenylamine (L) is described. The solidstate structures of 1, 2a, and 2b have been determined by center.

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