Aza-1,2,3-triazole-3-alanine Synthesis via Copper-Catalyzed 1,3-Dipolar Cycloaddition on Aza-progargylglycine
โ Scribed by Proulx, Caroline; Lubell, William D.
- Book ID
- 120278586
- Publisher
- American Chemical Society
- Year
- 2010
- Tongue
- English
- Weight
- 736 KB
- Volume
- 75
- Category
- Article
- ISSN
- 0022-3263
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๐ SIMILAR VOLUMES
2-Allyl-1,2,3-triazoles were prepared by the palladium-catalyzed three component coupling (TCC) reaction of alkynes, allyl methyl carbonate and trimethylsilyl azide. A p-allylpalladium azide complex, which undergoes the 1,3-dipolar cycloaddition with alkynes, is proposed as a key intermediate in the
## Key twxd.% I,3-Dipolar cycloaddidons; 2-Asa-1,3-butadienesi 2,3-Dehydroamino acIcIs; Sfteselectivity. ## Absawt : Tbe reactivfty and in partJcular the siteselectlvity of [3+2] electrocyclic additions to l,l-dJpJw?nyl-2-aza -1,3-butadknes, substftuted or not on tie term&M carbon wltb metiyJ and