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Axial Ligand Exchange of N -heterocyclic Cobalt(III) Schiff Base Complexes: Molecular Structure and NMR Solution Dynamics

✍ Scribed by Manus, Lisa M.; Holbrook, Robert J.; Atesin, Tulay A.; Heffern, Marie C.; Harney, Allison S.; Eckermann, Amanda L.; Meade, Thomas J.


Book ID
118203938
Publisher
American Chemical Society
Year
2013
Tongue
English
Weight
1000 KB
Volume
52
Category
Article
ISSN
0020-1669

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μ-η1:η1-N,N'-Imidazolidine-Bridged Dicop
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## Abstract The copper coordination chemistry of a new imidazolidine‐based doubly bridging μ‐bis(tetradentate) ligand, H~3~mhbai is studied. A new family of pentacoordinate dinuclear complexes of formula [Cu^II^~2~(‐mhbai)(‐X)]·2 H~2~O (1–4) [X = OAc, NO~3~, Cl, S~2~COMe], where H~3~mhbai stands fo