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Autorecycling oxidation of alcohol catalyzed by 1,3,7,9,11,12,14-heptazapentacene-2,4,8,10 (14H,3H,9H,12H)-tetraones (mixed flavins)

✍ Scribed by Fumio Yoneda; Masakazu Koga; Toshiro Ibuka

Book ID: 104242469
Publisher: Elsevier Science
Year: 1984
Tongue: French
Weight: 135 KB
Volume: 25
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(01)91279-1

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✦ Synopsis

tetraones (mixed flavins) were prepared by the cyclizatron of 1,5=dihydro-8-[N-alkyl-N-(5-nitrouracil-6-yl)-amino-5-deazaflavins with Vilsmeier reagent.

The mixed flavins oxidized alcohol under neutral condition in sunlight and a remarkable autorecycling was observed.

Recently it was shown that 5-deazaflavins which are regarded as NAD' in flavin clothing are able to oxidize alcohols 1) and amines2) nonenzymatically and

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