𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Automation of electrode kinetics—IV. The chlorine evolution reaction on a RuO2-TiO2 plate electrode

✍ Scribed by D.A. Denton; J.A. Harrison; R.I. Knowles

Publisher
Elsevier Science
Year
1980
Tongue
English
Weight
399 KB
Volume
25
Category
Article
ISSN
0013-4686

No coin nor oath required. For personal study only.

✦ Synopsis

TheCl, evolution reaction on RuO,-TiO, plate electrodes in 1M HCl has been studied by steady state i-E curves and (IC impedance using a new automated electrochemical measurement and display system. The characteristic electrochemical parameters are derived which will determine theindustrial performance. of the electrodes. NOMENCLATURE : Differential capacity per unit pore length. k&f Differential capacity. Standard rate at E". KV Ohmic resistance. R Charge transfer resistance per unit pore length. R Solution resistance per unit pore length. Z(w) Impedance. e Charge transfer resistance.

📜 SIMILAR VOLUMES

Chlorine and oxygen evolution on various
Chlorine and oxygen evolution on various compositions of RuO2/TiO2 electrodes
✍ I.R. Burrows; D.A. Denton; J.A. Harrison 📂 Article 📅 1978 🏛 Elsevier Science 🌐 English ⚖ 594 KB

## Thechlorine and oxygen evolution reactions have been investigated on various compositions of Ti supported Ru0,/Ti02 anodes. Conclusions have been reached on the structure of the electrode, and its influence on the mechanism of these two reactions, at the different compositions of Ru0JI'i02.

A consideration of the activation energy
A consideration of the activation energy for the chlorine evolution reaction on RuO2 and IrO2 electrodes
✍ Meguru Inai; Chiaki Iwakura; Hideo Tamura 📂 Article 📅 1979 🏛 Elsevier Science 🌐 English ⚖ 349 KB

Aba&act -The electrocatalysis for the chlorine evolution reaction on RuOs and Ir02 electrodes was &US& on the ba.& of& activation energy. The activated complex with the pentagonal bipyramid-type structure was speculated to be formed in the transition state for the Heymvsky reaction. The activation e

Kinetics of the hydrogen evolution react
Kinetics of the hydrogen evolution reaction on a rhodium electrode
✍ Piotr K. Wrona; Andrzej Lasia; Martin Lessard; Hugues Ménard 📂 Article 📅 1992 🏛 Elsevier Science 🌐 English ⚖ 934 KB

Ahstrae-Kinetics of the hydrogen evolution reaction (her) were measured at a rhodium electrode in a 1 M solution of KOH at various temperatures between 5 and 75°C. The rn-ts were conducted at a Rh wire electrode activated before every measurement by cycling in the range of potentials between -1.0 an

The effect of RuO2/TiO2 ratio on the rat
The effect of RuO2/TiO2 ratio on the rate of an outer-sphere electron transfer reaction on mixed oxide electrodes
✍ L. Tomcsányi; F. Molnár; J. Liszi; A. de Battisti 📂 Article 📅 1994 🏛 Elsevier Science 🌐 English ⚖ 361 KB

The apparent heterogeneous rate constants can be determined by a special cu technique in solutions containing both the oxidized and the reduced forms of a redox couple. The electrode materials are characterized by the dikence between the ktX and kFed. The effect of RuO,/IiO, ratio on the electrochem