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Automatic Assignment of Absolute Configuration from 1D NMR Data

✍ Scribed by Zhang, Qing-You; Carrera, Gonçalo; Gomes, Mário J. S.; Aires-de-Sousa, João

Book ID
127364705
Publisher
American Chemical Society
Year
2005
Tongue
English
Weight
452 KB
Volume
70
Category
Article
ISSN
0022-3263

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In the course of continuing studies of sesquiterpene oligosaccharides, Mukuroziosides, we have found that 'H NMR signal of C,\* -methylene proton for the diastereomeric pairs of @)and (S)-MTPA[a-methoxy-a-trifluoromethylphenyl acetic acid] 1) esters of Mukurozidiol(L) appears as distinctly different