Chiral Thiols: The Assignment of Their Absolute Configuration by 1 H NMR
✍ Scribed by Porto, Silvia; Seco, José Manuel; Ortiz, Aurelio; Quiñoá, Emilio; Riguera, Ricardo
- Book ID
- 121834255
- Publisher
- American Chemical Society
- Year
- 2007
- Tongue
- English
- Weight
- 185 KB
- Volume
- 9
- Category
- Article
- ISSN
- 1523-7060
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In the course of continuing studies of sesquiterpene oligosaccharides, Mukuroziosides, we have found that 'H NMR signal of C,\* -methylene proton for the diastereomeric pairs of @)and (S)-MTPA[a-methoxy-a-trifluoromethylphenyl acetic acid] 1) esters of Mukurozidiol(L) appears as distinctly different
## Abstract The carbon–carbon connectivity of terreinol, a new metabolite isolated from __Aspergillus terreus__, and its previous ^13^C assignments were confirmed by a two‐dimensional INADEQUATE experiment using a few milligrams of the compound with natural ^13^C abundance. The carbon–carbon correl