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Aurophilicity as a cofactor in crystal engineering. Dicyanoaurate(i) anion as a building block in a novel Co(ii)–Au(i) bimetallic assembly

✍ Scribed by Colacio, Enrique; Lloret, Francesc; Kivekäs, Raikko; Ruiz, José; Suárez-Varela, José; Sundberg, Markku R.


Book ID
120173794
Publisher
Royal Society of Chemistry
Year
2002
Tongue
English
Weight
142 KB
Volume
6
Category
Article
ISSN
1359-7345

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The reactions of water-soluble phosphanes P(CH,OH), (1) and Ph2PCH20H (2) with NaAuC14 in aqueous or alcoholic media, produced the water/alcoholic-soluble Au' complexes [Au(P(CH,OH),),]+ (3) and [Au(Ph2PCH20H):J+ (4) in near quantitative yields. The X-ray structures of 3 and 4, reported in this pape