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Attachment rate of thermal electrons to SF6

✍ Scribed by F.J. Davis; D.R. Nelson


Book ID
103010266
Publisher
Elsevier Science
Year
1970
Tongue
English
Weight
157 KB
Volume
6
Category
Article
ISSN
0009-2614

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πŸ“œ SIMILAR VOLUMES


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Thermochemical analysis of the electron capture process of SFs leads to a rate constant for the reverse process SF; 2 SF6 + e-, k 2 = 1.5 X 1013-31'.4/H s-l, where 0 = 2.303RT, in kcal/mol. The electron affinity of 32 f 3 kcal/mol is deduced from the observed bimolecularity of the capture process do

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We report here on the detection of (SFs),,.X-(X= SFs, SF+ SFs) ions which form by electron attachment to SF6 clusters in a molecular beam. The formation of some species, e.g. SFs,SFF with resonances at 6 and 10 eV, is unexpected because attachment to the bare SF, molecule does not yield the analogou