Atomic polarization in the photodissociation of diatomic molecules
β Scribed by Clark, A. P.; Brouard, M.; Quadrini, F.; Vallance, C.
- Book ID
- 119972825
- Publisher
- Royal Society of Chemistry
- Year
- 2006
- Tongue
- English
- Weight
- 801 KB
- Volume
- 8
- Category
- Article
- ISSN
- 1463-9076
- DOI
- 10.1039/B612590E
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The reaction IzM + hu-12( B) + M is studied followmg excitation of the 12M cluster above its B state dissoctation limit with M being the diatomics Hz, Nz, 0, and I\*. Dispersion of the iodine fluorescence allows for the determination of the relative populations of a number of the vibrational levels
## Abstract The restricted SCF (singleβconfiguration SCF) and MCSCF (multiconfiguration SCF) calculations are performed to compute the groundβstate electric dipole moments of four pairs of diatomic moleculesβ(1) CO and BF; (2) SiO and AlF; (3) CS and BCl; and (4) SiS and AlClβat a number of internu