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Atom Transfer Radical Polymerization of vinyl monomers mediated by a new class of neutral and cationic ruthenium alkylidene catalysts containing a 1,3-dimesityl-4,5-dihydroimidazol-2-ylidene and a Schiff base ligand

✍ Scribed by Bob De Clercq; Francis Verpoort


Book ID
106000679
Publisher
Springer
Year
2003
Tongue
English
Weight
495 KB
Volume
50
Category
Article
ISSN
0170-0839

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Activity of a new class of ruthenium bas
✍ Bob De Clercq; Francis Verpoort πŸ“‚ Article πŸ“… 2002 πŸ› Elsevier Science 🌐 French βš– 125 KB

A new class of ruthenium based catalysts coordinated with a 1,3-dimesityl-4,5-dihydroimidazol-2-ylidene and a Schiff base ligand have been tested in ring-closing metathesis and ring-opening metathesis polymerization reactions. The results obtained point out that the synergy of Schiff base ligands wi