Atom Transfer Radical Polymerization of Styrene Using a Novel Octafunctional Initiator: Synthesis of Well-Defined Polystyrene Stars
✍ Scribed by Angot, Stéphanie; Murthy, K. Shanmugananda; Taton, Daniel; Gnanou, Yves
- Book ID
- 111869843
- Publisher
- American Chemical Society
- Year
- 1998
- Tongue
- English
- Weight
- 100 KB
- Volume
- 31
- Category
- Article
- ISSN
- 0024-9297
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Controlled free radical polymerization of sugar-carrying methacrylate, 3-Omethacryloyl-1,2 : 5,6-di-O-isopropylidene-D-glucofuranose (MAIpGlc) was achieved by the atom transfer radical polymerization (ATRP) technique with an alkyl halide/coppercomplex system in veratrole at 80°C. The time-conversion
## Abstract Mono and difunctional polystyrenes containing active halogenated end groups were prepared by atom transfer radical polymerization (ATRP). Substitution reactions were explored to convert the halogen termini to azido groups, followed by readuction to form the amino functional polymer. Qua