## Abstract In the atom transfer radical polymerization (ATRP) of methyl methacrylate in the presence of [RuCl~2~(__p__‐cymene)(PCy~3~)] (__p__‐cymene = 4‐isopropyltoluene, PCy~3~ = tricyclohexylphosphine), a microwave effect is noted which strikingly depends on both the temperature and the method
Atom Transfer Radical Polymerisation with an Immobilised [RuCl2(p-cymene)]2 Dimer
✍ Scribed by T. Opstal; K. Melis; F. Verpoort
- Book ID
- 110351130
- Publisher
- Springer US
- Year
- 2001
- Tongue
- English
- Weight
- 131 KB
- Volume
- 74
- Category
- Article
- ISSN
- 1011-372X
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
## Abstract **Summary:** Polystyrene with high amounts of end‐labeling was synthesized using initiating systems comprised of conventional radical initiators and 2,7‐dibromofluorene or other fluorene derivatives in an adaptation of reverse atom transfer radical polymerization (RATRP). Benzoyl peroxi
## Based on competitive reactions and 1 H NMR measurements, it was found that (EtO) 2 P(O)CH 2 I is at least 2-3 orders of magnitude less reactive than other non-phosphorus iodides of the EWG-CH 2 I type (EWG = NC, COOMe, 4-Br-C 6 H 4 CO). MeSCH 2 I turned out to be totally unreactive in the title