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Atmospheric chemistry of hydrofluorocarbon 134a: fate of the alkoxy radical 1,2,2,2-tetrafluoroethoxy

✍ Scribed by Wallington, Timothy J.; Hurley, M. D.; Ball, James C.; Kaiser, Edward W.


Book ID
127300779
Publisher
American Chemical Society
Year
1992
Tongue
English
Weight
971 KB
Volume
26
Category
Article
ISSN
0013-936X

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## Abstract Smog chamber/FTIR techniques were used to study the Cl atom initiated oxidation of CH~2~FOCH~2~F in 700 Torr of N~2~/O~2~ at 296 K. Relative rate techniques were used to measure __k__(Cl + CH~2~FOCH~2~F) = (4.6 Β± 0.7) Γ— 10^βˆ’13^ and __k__(Cl + CH~2~FOC(O)F) = (2.9 Β± 0.8) Γ— 10^βˆ’15^ (in un