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Atmospheric Chemistry of CF 2 BrH: Kinetics and Mechanism of Reaction with F and Cl Atoms and Fate of CF 2 BrO Radicals

✍ Scribed by Bilde, Merete; Sehested, Jens; Møgelberg, Trine E.; Wallington, Timothy J.; Nielsen, Ole J.


Book ID
127183228
Publisher
American Chemical Society
Year
1996
Tongue
English
Weight
554 KB
Volume
100
Category
Article
ISSN
0022-3654

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Atmospheric chemistry of CH2FOCH2F: Reac
✍ M. Goto; M. Kawasaki; T. J. Wallington; M. D. Hurley; A. P. Sharratt 📂 Article 📅 2002 🏛 John Wiley and Sons 🌐 English ⚖ 185 KB

## Abstract Smog chamber/FTIR techniques were used to study the Cl atom initiated oxidation of CH~2~FOCH~2~F in 700 Torr of N~2~/O~2~ at 296 K. Relative rate techniques were used to measure __k__(Cl + CH~2~FOCH~2~F) = (4.6 ± 0.7) × 10^−13^ and __k__(Cl + CH~2~FOC(O)F) = (2.9 ± 0.8) × 10^−15^ (in un