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Asymmetric Weitz−Scheffer Epoxidation of Isoflavones with Hydroperoxides Mediated by Optically Active Phase-Transfer Catalysts

✍ Scribed by Adam, Waldemar; Rao, Paraselli Bheema; Degen, Hans-Georg; Levai, Albert; Patonay, Tamás; Saha-Möller, Chantu R.


Book ID
118070303
Publisher
American Chemical Society
Year
2002
Tongue
English
Weight
79 KB
Volume
67
Category
Article
ISSN
0022-3263

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Asymmetric epoxidation of hydrocarbon ol
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Catalytic enantioselective epoxidation of prochiral olefins without functional groups was achieved by tert-BuOOH using Mo(0)2(acac)2 -optically active diols as catalysts. In spite of dramatic developements in asymmetric hydrogenations using optically active transition metal catalysts during recent y