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Asymmetric weitz - scheffer epoxidation promoted by bovine serum albumin: Part III. Highly stereoselective synthesis of optically active epoxynaphthoquimones

โœ Scribed by Stefano Colona; Nicoletta Gaggero; Amedea Manfredil; Massimo Spadoni; Luigi Casella; Giacomo Carrea; Piero Pasta


Publisher
Elsevier Science
Year
1988
Tongue
French
Weight
744 KB
Volume
44
Category
Article
ISSN
0040-4020

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Catalytic asymmetric weitz-scheffer epox
โœ Stefano Colonna; Amedea Manfredi; Rita Annunziata; Massimo Spadoni ๐Ÿ“‚ Article ๐Ÿ“… 1987 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 455 KB

The epoxidation of 2 and 2,3-substituted naphthoquinones with t-BuOOH In aqueous buffer solutions, in the presence of bovine serum albumin (BSA) as chiral catalyst, affords the corresponding epoxynaphthoquinones with enantiomeric excess (e.e.1 up to 79%. The influences on the enantioselectivity of t