Asymmetric Transfer Hydrogenation of Ketones Catalyzed by Enantiopure Osmium(II) Pybox Complexes
β Scribed by Vega, Esmeralda; Lastra, E.; Gamasa, M. Pilar
- Book ID
- 120276499
- Publisher
- American Chemical Society
- Year
- 2013
- Tongue
- English
- Weight
- 442 KB
- Volume
- 52
- Category
- Article
- ISSN
- 0020-1669
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## Abstract The osmium compound __trans__,__cis__β[OsCl~2~(PPh~3~)~2~(Pyme)] (1) (Pyme=1β(pyridinβ2βyl)methanamine), obtained from [OsCl~2~(PPh~3~)~3~] and Pyme, thermally isomerizes to __cis__,__cis__β[OsCl~2~(PPh~3~)~2~(Pyme)] (2) in mesitylene at 150βΒ°C. Reaction of [OsCl~2~(PPh~3~)~3~] with Ph~
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