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Asymmetric hydrogenations of ketones catalyzed by Ru–achiral phosphine-enantiopure diamine complexes

✍ Scribed by Yu-Qing Xia; Yuan-You Tang; Zhi-Ming Liang; Chang-Bin Yu; Xiang-Ge Zhou; Rui-Xiang Li; Xian-Jun Li

Book ID
108211563
Publisher
Elsevier Science
Year
2005
Tongue
English
Weight
190 KB
Volume
240
Category
Article
ISSN
1381-1169

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Ru–η6-benzene–phosphine complex-catalyze
Ru–η6-benzene–phosphine complex-catalyzed transfer hydrogenation of ketones
✍ Lei Wang; Qin Yang; Hai-Yan Fu; Hua Chen; Mao-Lin Yuan; Rui-Xiang Li 📂 Article 📅 2011 🏛 John Wiley and Sons 🌐 English ⚖ 210 KB

## Abstract Three Ru–η^6^‐benzene–phosphine complexes bearing tri‐(__p__‐methoxyphenyl)phosphine, triphenylphosphine and tri‐(__p__‐trifluoromethylphenyl)phosphine were synthesized and characterized by ^31^P{^1^H} NMR, ^1^H NMR, ^13^C{^1^H} NMR and elemental analyses. Complex 1 was further identifi