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Asymmetric Transfer Hydrogenation: Chiral Ligands and Applications

✍ Scribed by Serafino Gladiali; Elisabetta Alberico


Publisher
John Wiley and Sons
Year
2006
Weight
8 KB
Volume
37
Category
Article
ISSN
0931-7597

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✦ Synopsis


Abstract

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## Abstract A new chiral aminophosphine ligand 6,6′‐dimethoxy‐2,2′‐bis(diphenylphosphinoamino) biphenyl (DMBDPPABP) was prepared and its rhodium complex was found to be an effective catalyst for the asymmetric hydrogenation of amidoacrylic add and its derivatives. The effects of solvent and reactio