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Asymmetric transamination from amino acids (II) asymmetric synthesis of amines by chemical transamination of optically active amino acids to ketones

✍ Scribed by Shun-ichi Yamada; Nobuo Ikota; Kazuo Achiwa


Book ID
108380104
Publisher
Elsevier Science
Year
1976
Tongue
French
Weight
204 KB
Volume
17
Category
Article
ISSN
0040-4039

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## Abstract Enantioselective synthesis of phenylalanine was performed by reacting phenylpyruvic acid with pyridoxamine followed by ketimine‐aldimine isomerization of the __Schiff__ base formed catalyzed by an optically active copper (II)‐complex. By UV and CD measurements it was shown that the enan