𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Asymmetric total synthesis of (+)-goniotriol and (+)-goniofufurone

✍ Scribed by Zhi-cai Yang; Wei-shan Zhou

Publisher
Elsevier Science
Year
1995
Tongue
French
Weight
417 KB
Volume
51
Category
Article
ISSN
0040-4020

No coin nor oath required. For personal study only.

πŸ“œ SIMILAR VOLUMES

Total synthesis of antitumor agents, (+)
Total synthesis of antitumor agents, (+)-goniopypyrone and (+)-7-epi-goniofufurone
✍ Jean-Philippe Surivet; Jean-Michel VatΓ¨le πŸ“‚ Article πŸ“… 1997 πŸ› Elsevier Science 🌐 French βš– 126 KB

Synthesis of enantiopure (+)-7-epi-goniofufurone 1 and (+)-goniopypyrone 2 has been achieved from C-4 carbon chain chiron 3, readily available from (R)-mandelic acid.

Application of the reaction of D-glucose
Application of the reaction of D-glucose with meldrum's acid: Total synthesis of the styryl lactones (+)-goniofufurone and (+)-7-epi-goniofufurone
✍ Rainer Bruns; Angelika Wernicke; Peter KoΒ¨ll πŸ“‚ Article πŸ“… 1999 πŸ› Elsevier Science 🌐 French βš– 450 KB

The syntheses of the styryl lactones (+)-goniofufurone ( ) and (+)-7-epi-goniofufurone (2) from Dglucose are presented. The key steps are the formation of the lactone moiety by reaction of the hemiace~ais 15 and 16 with meldrum's acid (3) and the addition of phenylmagnesium bromide to the aldehydes