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Asymmetric Total Synthesis of (+)-Aphanamol I Based on the Transition Metal Catalyzed [5 + 2] Cycloaddition of Allenes and Vinylcyclopropanes

✍ Scribed by Wender, Paul A.; Zhang, Lei


Book ID
121348581
Publisher
American Chemical Society
Year
2000
Tongue
English
Weight
61 KB
Volume
2
Category
Article
ISSN
1523-7060

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ChemInform Abstract: The First Metal-Cat
✍ P. A. WENDER; C. O. HUSFELD; E. LANGKOPF; J. A. LOVE; N. PLEUSS πŸ“‚ Article πŸ“… 2010 πŸ› John Wiley and Sons βš– 37 KB πŸ‘ 2 views

The First Metal-Catalyzed Intramolecular [5 + 2] Cycloadditions of Vinylcyclopropanes and Alkenes: Scope, Stereochemistry, and Asymmetric Catalysis. -This novel cycloaddition works well with a wide variety of substrates, and generally proceeds with exceptional diastereoselectivity and in good to exc