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Asymmetric Total Syntheses of (−)-Renieramycin M and G and (−)-Jorumycin Using Aziridine as a Lynchpin

✍ Scribed by Wu, Yan-Chao; Zhu, Jieping


Book ID
121491610
Publisher
American Chemical Society
Year
2009
Tongue
English
Weight
688 KB
Volume
11
Category
Article
ISSN
1523-7060

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✍ S. YAO; M. JOHANNSEN; R. G. HAZELL; K. A. JOERGENSEN 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 33 KB

Total Synthesis of (R)-Dihydroactinidiolide and (R)-Actinidiolide Using Asymmetric Catalytic Hetero-Diels-Alder Methodology. -Key steps in the synthesis of title compounds (V) and (VI) are regio-and stereoselective hetero-Diels-Alder reaction of the diene (I) and subsequent rearrangement to the lac