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Asymmetric synthesis XVIII : Preparation of Chiral 1,2-diamines via the CN(R,S) Method. Application to the synthesis of an analogue of tetraponerine

✍ Scribed by Jieping Zhu; Jean-Charles Quirion; Henri-Philippe Husson

Publisher
Elsevier Science
Year
1989
Tongue
French
Weight
225 KB
Volume
30
Category
Article
ISSN
0040-4039

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✦ Synopsis

Preparation

of Chiral 1,2-diamines via the CN(R,S) Method. Application to the Synthesis of an Analogue of Tetraponerine. Jieping ZHU,

πŸ“œ SIMILAR VOLUMES

Asymmetric synthesis xx preparation of a
Asymmetric synthesis xx preparation of a novel spiropiperidine system by the CN(R,S) method
✍ Jieping Zhu; Jean-Charles Quirion; Henri-Philippe Husson πŸ“‚ Article πŸ“… 1989 πŸ› Elsevier Science 🌐 French βš– 172 KB

A novel spiropiperidine system i.e an aza structural analog of histrionicotoxin has been constructed from 2-cyano-6-phenyloxazolopiperidine synthon 3. The suitable quaternary carbon was created by alkylation at the position c~ ta the nitrile fallowed by transformation of the nitrile group into a pri